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<article language="en">
	<journal>
		<journal_title>The Cryosphere Discussions</journal_title>
		<journal_url>www.the-cryosphere-discuss.net</journal_url>
		<issn>1994-0432</issn>
		<eissn>1994-0440</eissn>
		<volume_number>4</volume_number>
		<issue_number>3</issue_number>
		<publication_year>2010</publication_year>
	</journal>
	<doi>10.5194/tcd-4-1525-2010</doi>
	<article_url>http://www.the-cryosphere-discuss.net/4/1525/2010/</article_url>
	<abstract_html>http://www.the-cryosphere-discuss.net/4/1525/2010/tcd-4-1525-2010.html</abstract_html>
	<fulltext_pdf>http://www.the-cryosphere-discuss.net/4/1525/2010/tcd-4-1525-2010.pdf</fulltext_pdf>
	<start_page>1525</start_page>
	<end_page>1559</end_page>
	<publication_date>2010-09-01</publication_date>
	<article_title content_type="html">First investigations of an ice core from Eisriesenwelt cave (Austria)</article_title>
	<authors>
		<author numeration="1" affiliations="1">
			<name>B. May</name>
			<email>barbara.may@iup.uni-heidelberg.de</email>
		</author>
		<author numeration="2" affiliations="2">
			<name>C. Spötl</name>
		</author>
		<author numeration="3" affiliations="1">
			<name>D. Wagenbach</name>
		</author>
		<author numeration="4" affiliations="2">
			<name>Y. Dublyansky</name>
		</author>
		<author numeration="5" affiliations="3">
			<name>J. Liebl</name>
		</author>
	</authors>
	<affiliations>
		<affiliation numeration="1" content_type="html">Institut für Umweltphysik, Universität Heidelberg, Im Neuenheimer Feld 229, 69120 Heidelberg, Germany</affiliation>
		<affiliation numeration="2" content_type="html">Institut für Geologie und Paläontologie, Lepold-Franzens-Universität Innsbruck, Innrain 52, 6020 Innsbruck, Austria</affiliation>
		<affiliation numeration="3" content_type="html">Vienna Environmental Research Accelerator (VERA), Fakultät für Physik – Isotopenforschung, Universität Wien, Währinger Straße 17, 1090 Wien, Austria</affiliation>
	</affiliations>
	<abstract content_type="html">Investigations into the genesis and dynamical properties of cave ice are
essential for assessing the climate significance of these underground
glaciers. We drilled an ice core through a 7.1 m thick ice body filling a
large cavern of the dynamic ice cave Eisenriesenwelt (Austria). In addition
to visual core inspections, quasi-continuous measurements at 2 cm resolution
comprised particulate matter, stable water isotope (&amp;delta;&lt;sup&gt;18&lt;/sup&gt;O,
&amp;delta;&lt;i&gt;D&lt;/i&gt;) and electrolytic conductivity profiles supplemented by
specifically selected samples analysed for tritium and radiocarbon. We found
that recent ablation led to an almost complete loss of bomb derived tritium
removing any ice accumulated, since at least, the early fifties leaving the
actual ice surface even below the natural tritium level. The small
particulate organic masses made radiocarbon dating inconclusive, though a
crude estimate gave a maximum ice age in the order of several thousand
years. The visual stratigraphy and all investigated parameters showed a
clear dichotomy between the upper 4 m and the bottom 3 m of the core, which
points to a substantial change in the ice formation process. Main features
of the core comprise the changing appearance and composition of distinct
cyro-calcite layers, a extremely low total ion content and a surprisingly
high variability of the isotope signature. Co-isotope evaluation (&amp;delta;&lt;i&gt;D&lt;/i&gt;
versus &amp;delta;&lt;sup&gt;18&lt;/sup&gt;O) of the core in comparison with data from
precipitation and karst spring water clearly indicate that ice formation is
governed by (slow) freezing of dripping water.</abstract>
	<references>
		<reference numeration="1" content_type="text"> Achleitner, A.: Zum Alter des Höhleneises in der Eisgruben-Eishöhle im Sarstein (Oberösterreich), Die Höhle, 46, 1–5, 1995. </reference>
		<reference numeration="2" content_type="text"> Austrian Network of Isotopes in Precipitation, Umweltbundesamt: http://www.umweltbundesamt.at/umweltinformation/wasser/isotopen/isotopen, last access: August~2010. </reference>
		<reference numeration="3" content_type="text"> Behm, M., Dittes, V., Greilinger, R., Hartmann, H., Plan, L., and Sulzbacher, D.: Decline of cave ice – a case study from the Austrian Alps (Europe) based on 416 years of observation, Proceedings 15th~Intern. Congr. Speleol., Kerrville, Texas, 3, 1413–1416, 2009. </reference>
		<reference numeration="4" content_type="text"> Behm, M. and Hausmann, H.: Eisdickenmessungen in alpinen Höhlen mit Georadar, Die Höhle, 58, 3–11, 2007. </reference>
		<reference numeration="5" content_type="text"> Bock, H.: Matematisch-physikalische Untersuchung der Eishöhlen und Windröhren, in: Die Höhlen im Dachstein, edited by: Bock, H., Lahner, G., and Gaunersdorfer, G., Verein für Höhlenkunde in Österreich, 102–144, 1913. </reference>
		<reference numeration="6" content_type="text"> Büntgen, U., Frank, D. C., Nievergelt, D., and Esper, J.: Summer temperature variations in the European Alps, A D 755–2004, J. Climate, 19, 5606–5623, 2006. </reference>
		<reference numeration="7" content_type="text"> Clausen, H. B., Vrana, K., Hansen, S. B., Larsen, L. B., Baker, J., Siggaard-Andersen, M.-L., Sjolte, J., and Lundholm, S. C.: Continental ice body in Dobsina ice cave (Slovakia) – Part~2: Results of chemical and isotopic study, Proc. 2nd~Int. Workshop on Ice Caves, 29–37, 2007. </reference>
		<reference numeration="8" content_type="text"> Dickfoss, P. V., Betancourt, J. L., Thompson, L. G., Turner, R. M., and Tharnstrom, S.: History of ice at Candelaria Ice Cave, New Mexico, New Mexico Bureau of Mines and Mineral Resources Bull., 156, 91–112, 1997. </reference>
		<reference numeration="9" content_type="text"> Frank, D. and Esper, J.: Temperature reconstructions and comparisons with instrumental data from a tree-ring network for the European Alps, Int. J. Climatol., 25, 1437–1454, 2005. </reference>
		<reference numeration="10" content_type="text"> Fröhlich, K., Kralik, M., Papesch, W., Rank, D., Scheifinger, H., and Stichler, W.: Deuterium excess in precipitation of Alpine regions – moisture recycling, Isot. Environ. Healt. S., 44(1), 61–70, 2008. </reference>
		<reference numeration="11" content_type="text"> Haeberli, W., Frauenfelder, R., Káäb, A., and Wagner, S.: Characteristics and potential significance of &quot;miniature ice caps&quot; (crest- and cornice-type low-latitude ice archives), J. Glaciol., 50(168), 129–136, 2004. </reference>
		<reference numeration="12" content_type="text"> Hauser, E. and Oedl, R.: Die große Eishöhle im Tennengebirge (Salzburg), (Eisriesenwelt), V Eisbildungen und meteorologische Beobachtungen, Speläol. Jb., 4, 17–47, 1922. </reference>
		<reference numeration="13" content_type="text"> Hauser, E. and Oedl, R.: Eisbildungen und meteorologische Beobachtungen, in: Die Eisriesenwelt im Tennengebirge (Salzburg), edited by: Angermayer, E., Asal, A., Czörnig-Czernhausen, W., Hauser, E., Lehmann, O., Oedl, R., Pia, J., and Wettstein-Westersheim, O., Speläologische Monographien, , Verlag Speläol. Inst., Wien, 6, 77–105, 1926. </reference>
		<reference numeration="14" content_type="text"> Holmlund, P., Onac, B. P., Hansson, M., Holmgren, K., Mörth, M., Nyman, M., and Persoiu, A.: Assessing the palaeoclimate potential of cave glaciers: the example of the Scarisoara Ice Cave (Romania), Geogr. Ann A, 87, 193–201, 2005. </reference>
		<reference numeration="15" content_type="text"> Jouzel, J. and Souchez, R. A.: Melting-refreezing at the glacier sole and the isotopic composition of the ice, J. Glaciol., 28(98), 35–42, 1982. </reference>
		<reference numeration="16" content_type="text"> Kern, Z., Molnár, M., Svingor, É., Persoiu, A., and Nagy, B.: High-resolution, well-preserved tritium record in the ice of Bortig Ice Cave, Bihor Mountains, Holocene, 19, 729–736, 2009. </reference>
		<reference numeration="17" content_type="text"> Kern, Z., Fórizs, I., Molnár, M., Nagy, B., and Pavuza, R.: Isotope hydrological studies on the perennial ice deposit of Saarhalle, Mammuthöhle, Dachstein Mts., Austria, under review for The Cryosphere Discuss., 2010. </reference>
		<reference numeration="18" content_type="text"> Killawee, J. A., Fairchild, I. J., Tison, J.-L., Janssens, L., and Lorrain, R.: Segregation of solutes and gases in experimental freezing of dilute solutions: implications for natural glacial systems, Geochim. Cosmochim. Acta, 62(23–24), 3637–3655, 1998. </reference>
		<reference numeration="19" content_type="text"> Klappacher, W. and Haseke-Knapczyk, H.: Salzburger Höhlenbuch, Vol 4, No 556, Salzburg, Landesverein für Höhlenkunde in Salzburg, 1985. </reference>
		<reference numeration="20" content_type="text"> Lehmann, O.: IV Morphologische Beobachtungen, Speläol. Jb., 3, 51–121, 1922. </reference>
		<reference numeration="21" content_type="text"> Lehmann, M. and Siegenthaler, U.: Equilibrium oxygen- and hydrogen-isotope fractionation between ice and water, J. Glaciol., 37(125), 23–26, 1991. </reference>
		<reference numeration="22" content_type="text"> Liebl, J., Avalos Ortiz, R., Golser, R., Handle, F., Kutschera, W., Steier, P., and Wild, E. M.: Studies on the preparation of small $^14$C samples with an RGA and $^13$C-enriched material, Radiocarbon, 52-2, 1394–1404, 2010. </reference>
		<reference numeration="23" content_type="text"> Luetscher, M.: Processes in ice caves and their significance for paleoenvironmental reconstructions, PhD thesis, Universität Zurich, 2005. </reference>
		<reference numeration="24" content_type="text"> Luetscher, M., Bolius, D., Schwikoswski, M., Schotterer, U., and Smart, P. L.: Comparison of techniques for dating of subsurface ice from Monlesi ice cave, Switzerland, J. Glaciol., 53, 374–384, 2007. </reference>
		<reference numeration="25" content_type="text"> Mais, K. and Pavuza, R.: Hinweise zu Höhlenklima und Höhleneis in der Dachstein-Mammuthöhle (Oberösterreich), Die Höhle, 51, 121–125, 2000. </reference>
		<reference numeration="26" content_type="text"> Mangini, A., Spötl, C., and Verdes, P.: Reconstruction of temperature in the Central Alps during the past 2000 years from a δ18O stalagmite record, Earth Planet. Sc. Lett., 235, 741–751, 2005. </reference>
		<reference numeration="27" content_type="text"> Mangini, A., Verdes, P., Spötl, C., Scholz, D., Vollweiler, N., and Kromer, B.: Persistent influence of the North Atlantic hydrography on Central European winter temperature during the last 9,000 years, Geophys. Res. Lett., 34, L02704, doi:10.1029/2006GL028600, 2007. </reference>
		<reference numeration="28" content_type="text"> May, B.: Radiocarbon microanalysis on ice impurities for dating of Alpine glaciers, Dissertation, Universität Heidelberg, 2009. </reference>
		<reference numeration="29" content_type="text"> Nderichuk, V. and Dorofeev, E.: The influence of natural and anthropogenous factors on temperature regime and ice formations of Kungur Cave (Russia), Theor. Appl. Karstol., 7, 149–153, 1994. </reference>
		<reference numeration="30" content_type="text"> Obleinter, F. and Spötl, C.: The mass and energy balance of ice within the Eisriesenwelt cave, Austria, submitted to The Cryosphere Discuss., 2010. </reference>
		<reference numeration="31" content_type="text"> Oerlemans, J.: Extracting a climate signal from 169~glacier records, Science, 308, 675–677, 2005. </reference>
		<reference numeration="32" content_type="text"> Ohata, T., Furukawa, T., and Higuchi, K.: Glacioclimatological study of perennial ice in the Fuji ice cave, Japan, Part~1, Seasonal variation and mechanism of maintenance, Arctic Alpine Res., 26, 227–237, 1994a. </reference>
		<reference numeration="33" content_type="text"> Ohata, T., Furukawa, T., and Osada, K.: Glacioclimatological study of perennial ice in the Fuji ice cave, Japan, Part~2, Interannual variation and relation to climate, Arctic Alpine Res., 26, 238–244, 1994b. </reference>
		<reference numeration="34" content_type="text"> Pavuza, R.: Updated data on ice development in some Austrian caves, 4th~Intern. Workshop on Ice Caves, Obertrau, Austria, Abstract, 28, 2010. </reference>
		<reference numeration="35" content_type="text"> Pavuza, R. and Mais, K.: Aktuelle höhlenklimatische Aspekte der Dachstein-Rieseneishöhle, Die Höhle, 50, 126–140, 1999. </reference>
		<reference numeration="36" content_type="text"> Pavuza, R. and Spötl, C.: Neue Forschungsergebnisse aus der Hundalm-Eishöhle (1266/1), Höhlenkundliche Mitteilungen Landesverein für Höhlenkunde Tirol, 38, 3–10, 2000. </reference>
		<reference numeration="37" content_type="text"> Persoiu, A., Onac, B., and Feurdean, A.: Multi-proxy climatic and environmental record for the last 1000~years in the western Carpathians, Romania, 4th~Intern. Workshop on Ice Caves, Obertrau, Austria, Abstract, 29, 2010. </reference>
		<reference numeration="38" content_type="text"> Saar, R.: Eishöhlen, ein meteorologisch-geophysikalisches Phänomen, Geografiska Annaler, 38, 1–63, 1956. </reference>
		<reference numeration="39" content_type="text"> Scheidleder, A., Boroviczeny, F., Graf, W., Hofmann, T., Mandl, G., Schubert, G., Stichler, W., Trimborn, P., and Kralik, M.: &quot;KARSTWASSER DACHSTEIN&quot;, Band~2: Karsthydrologie und Kontaminationsrisiko von Quellen, Umweltbundesamt Österreich, http://www.umweltbundesamt.at/fileadmin/site/publikationen/M108.pdf, last access: August~2010, Monographien Band~108, 2001. </reference>
		<reference numeration="40" content_type="text"> Souchez, R. A. and de Groote, J. M.: $\deltaD$-and $\delta^18$O relationships in ice formed by subglacial freezing: Paleoclimatic implications, J. Glaciol., 31(109), 369–372, 1985. </reference>
		<reference numeration="41" content_type="text"> Spötl, C. and Vennemann, T.: Continuous-flow IRMS analysis of carbonate minerals, Rapid Commun. Mass Sp., 17, 1004–1006, 2003. </reference>
		<reference numeration="42" content_type="text"> Spötl, C.: Kryogene Karbonate im Höhleneis der Eisriesenwelt, Die Höhle, 59, 26–36, 2008. </reference>
		<reference numeration="43" content_type="text"> Steier, P., Drosg, R., Fedi, M., Kutschera, W., Schock, M., Wagenbach, D., Wild, E. M.: Radiocarbon determination of particulate organic carbon in non-temperated, Alpine glacier ice, Radiocarbon, 48, 69–82, 2006. </reference>
		<reference numeration="44" content_type="text"> Stoffel, M., Luetscher, M., Bollschweiler, M., and Schlatter, F.: Evidence of NAO control on subsurface ice accumulation in a 1200 yr old cave-ice sequence, St Livres ice cave, Switzerland, Quaternary. Res., 72, 16–26, 2009. </reference>
		<reference numeration="45" content_type="text"> Von Grafenstein, U., Erlenkeuser, H., Brauer, A., Jouzel, J., and Johnsen, S. J.: A mid-European decadal isotope-climate record from 15,000 to 5000 years B.P., Science, 284, 1654–1657, 1999. </reference>
		<reference numeration="46" content_type="text"> Vrana, K., Baker, J., Clausen, H. B., Hansen, S. B., Zelinka, J., Rufli, H., Oèkaik, L., and Janoèko, J.: Continental ice body in Dobsina ice cave (Slovakia) – Part~1, Project and sampling phase of isotopic and chemical study, Proc. 2nd~Int. Workshop on Ice Caves, 24–28, 2007. </reference>
		<reference numeration="47" content_type="text"> Wimmer, M.: Eis- und Lufttemperaturmessungen im Schönberg-Höhlensystem (1626/300) und Modellvorstellungen über den Eiszyklus, Die Höhle, 59, 13–25, 2008. </reference>
		<reference numeration="48" content_type="text"> Yonge, C. J. and Macdonald, W. D.: The potential of perennial cave ice in isotope palaeoclimatology, Boreas, 28, 357–362, 1999. </reference>
		<reference numeration="49" content_type="text"> Žák, K., Onac, B. P., Perşoiu, A.: Cryogenic carbonates in cave invironments: A review, Quatern. Int., 187, 84–96, 2008. </reference>
	</references>
</article>

